Document Detail
The effect of mulitivalent cation dopants on lithium manganese spinel cathodes
Abstract/OtherAbstract :
The aim of this investigation is to determine optimised spinel cathode compositions that can be used in lithium cells. The cycling stability of 4 V LixMn2O4 electrodes in lithium, flooded electrolyte glass cells has been improved by the addition of multivalent cation dopants (Mg2+,Zn2+ and Al3+). Optimal dopant levels to achieve maximum capacity and the greatest stability with repeated cycling have been determined. The effect of doping the oxygen-rich-spinel Li2Mn4O9 was also determined and shown to make no significant improvement in the life cycle stability in the 3 V region.
Authors :
De Kock, A, Freg, E, Gummow, RJ
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Contributors :
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Publication Detail :
Publisher :  Elsevier Science SA     Type :  Article     Format :  482664 bytes, application/pdf    
Date Detail :
2007-01-12, 2007-06-07, 2007-01-12, 2007-06-07, 1998-02
Subject :
Lithium manganese, Spinel, Cation doping
Coverage :
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Relation :
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Source :
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Copyright Information :
Copyright: 1998 Elsevier Science SA
Other Details :
Languages :  en    
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