Document Detail


A versatile synthesis for new 9,10-bis(4-alkoxyphenyl)-2,7-diiodophenanthrenes: useful precursors for conjugated polymers.
MedLine Citation:
PMID:  17629293     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
A practical synthesis for 9,10-bis(alkoxyphenyl)-2,7-diiodophenanthrenes is described. 9,10-Bis(4-hexyloxyphenyl)-2,7-diiodophenanthrene was selectively obtained by a one-pot reaction of 10,10-bis-(4-hexyloxy-phenyl)-2,7-diiodo-10H-phenanthren-9-one with 1 equiv of triethylsilane in trifluoroacetic acid. The target molecular architecture was demonstrated to be a useful precursor for obtaining the corresponding poly(phenanthrene) and poly(phenanthrylene-vinylene).
Authors:
Roberto Grisorio; Gian Paolo Suranna; Piero Mastrorilli; Cosimo Francesco Nobile
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Publication Detail:
Type:  Journal Article     Date:  2007-07-13
Journal Detail:
Title:  Organic letters     Volume:  9     ISSN:  1523-7060     ISO Abbreviation:  Org. Lett.     Publication Date:  2007 Aug 
Date Detail:
Created Date:  2007-07-26     Completed Date:  2007-09-04     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  3149-52     Citation Subset:  -    
Affiliation:
Department of Water Engineering and of Chemistry, Polytechnic of Bari, Campus Universitario, via Orabona 4-Bari, Italy.
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