| A soluble-polymer system for the asymmetric transfer hydrogenation of ketones. | |
| | |
MedLine Citation:
|
PMID: 15287789 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
|
The appropriate combination of methacrylate polymers permits the synthesis of a soluble polymer for use in ruthenium(II)-catalyzed asymmetric transfer hydrogenation reactions. Using a 7:3 copolymer of a poly(ethylene glycol) ester and a hydroxyethyl ester, a derived ruthenium(II)/norephedrine complex catalyses reduction of acetophenone in up to 95% yield and 81% ee. |
| | |
Authors:
|
Stephanie Bastin; Richard J Eaves; Christopher W Edwards; Osamu Ichihara; Mark Whittaker; Martin Wills |
Related Documents
:
|
17264909 - Highly enantioselective nitroaldol reaction catalyzed by new chiral copper complexes. 20939099 - Cu(i)-catalyzed asymmetric chlorination of β-keto esters in the presence of chiral pho... 22921589 - The h(2)o(2)-sensitive hyper protein targeted to the endoplasmic reticulum as a mirror ... 12735749 - Bridgehead enolates: substitution and asymmetric desymmetrization of small bridged carb... 17464409 - Preparation of new axially chiral bridged 2,2'-bipyridines and pyridyl monooxazolines (... 10672459 - Developing a chiral toolbox for asymmetric catalytic reactions. 8794159 - The different conformations of the glycerol region of crystalline acylglycerols. 23074889 - Royleanumin, a new phytotoxic neo-clarodane diterpenoid from teucrium royleanum. 12470059 - Molecular structures of two metal tetrakis(tetrahydroborates), zr(bh4)(4) and u(bh4)(4)... |
Publication Detail:
|
Type: Journal Article |
Journal Detail:
|
Title: The Journal of organic chemistry Volume: 69 ISSN: 0022-3263 ISO Abbreviation: J. Org. Chem. Publication Date: 2004 Aug |
Date Detail:
|
Created Date: 2004-08-03 Completed Date: 2004-09-08 Revised Date: - |
Medline Journal Info:
|
Nlm Unique ID: 2985193R Medline TA: J Org Chem Country: United States |
Other Details:
|
Languages: eng Pagination: 5405-12 Citation Subset: - |
Copyright Information:
|
Copyright 2004 American Chemical Society |
Affiliation:
|
Department of Chemistry, University of Warwick, Coventry CV4 7AL, U.K. |
Export Citation:
|
APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
|
|
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
Previous Document: Kinetics and mechanism of the pyridinolysis of s-4-nitrophenyl 4-substituted thiobenzoates in aqueou...
Next Document: New approach to indole alkaloids based on the intramolecular Pauson-Khand reaction.