Document Detail


A series expansion of the extended Debye-Hückel equation and application to linear prediction of stability constants.
MedLine Citation:
PMID:  18966639     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
The Debye-Hückel semiempirical extended equation is frequently used to calculate activity coefficients of chemical species and equilibrium constants at ionic strengths different from those used in their experimental evaluation. A series expansion of the extended Debye-Hückel equation is proposed here and checked with experimental data taken from the literature. The expansion is linear in the ionic parameters and yields a geometrical series which converges rapidly and that enables the accurate calculation of interpolated and extrapolated activity coefficients and equilibrium constants by simple and multiple linear regression without previous knowledge of the ionic parameters.
Authors:
J J Baeza Baeza; G Ramis-Ramos
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Talanta     Volume:  43     ISSN:  0039-9140     ISO Abbreviation:  Talanta     Publication Date:  1996 Sep 
Date Detail:
Created Date:  2008-10-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2984816R     Medline TA:  Talanta     Country:  England    
Other Details:
Languages:  eng     Pagination:  1579-87     Citation Subset:  -    
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