| A practical route to tertiary diarylmethylamides or -carbamates from imines, organozinc reagents and acyl chlorides or chloroformates. | |
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MedLine Citation:
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PMID: 21915199 Owner: NLM Status: In-Data-Review |
Abstract/OtherAbstract:
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A practical route to tertiary diarylmethylamides or -carbamates from imines, organozinc reagents and acyl chlorides or chloroformates is described. This route involves the formation of an imine, which is used without isolation, followed by its activation by the carbonyl-containing electrophile and the trapping of the acyliminium by an organozinc reagent. Most steps are conducted concomitantly to render the procedure as practical and straightforward as possible. Therefore, the whole experimental protocol takes less than two hours. |
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Authors:
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Erwan Le Gall; Antoine Pignon; Thierry Martens |
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Publication Detail:
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Type: Journal Article Date: 2011-07-20 |
Journal Detail:
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Title: Beilstein journal of organic chemistry Volume: 7 ISSN: 1860-5397 ISO Abbreviation: Beilstein J Org Chem Publication Date: 2011 |
Date Detail:
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Created Date: 2011-09-14 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101250746 Medline TA: Beilstein J Org Chem Country: Germany |
Other Details:
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Languages: eng Pagination: 997-1002 Citation Subset: - |
Affiliation:
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Électrochimie et Synthèse Organique, Institut de Chimie et des Matériaux Paris-Est, UMR 7182 CNRS - Université Paris-Est Créteil, 2-8 rue Henri Dunant, 94320 Thiais, France. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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