Document Detail


A novel synthesis of steryl esters from phytosterols and amino acid.
MedLine Citation:
PMID:  21879751     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The feasibility of esterification of phytosterol with amino acid L-Glutamic was established. The influence of various organic solvents was investigated and n-butanol was selected as an ideal solvent for phytosteryl esters synthesis with L-Glutamic. The reaction conditions were further optimized by orthogonal experiments and that 92.3% degree of esterification was obtained when operated in optimum conditions. FT-IR spectrum, GC-MS and NMR analysis were adopted to determine the steryl esters of L-Glutamic. The FT-IR spectrum indicated the presence of the ester bonds existed in the phytosteryl esters with L-Glutamic, and based on the detailed mass spectrography analysis, GC-MS and NMR offered an efficient and reliable way to confirm the steryl esters. This novel synthesis approach of phytosteryl esters with amino acid supplied a promising alternative of the substrate on esterification of phytosterols and thus can be readily applied to further studies of functional food ingredients of phytosteryl esters.
Authors:
Min Pang; Shaotong Jiang; Lili Cao; Lijun Pan
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-8-31
Journal Detail:
Title:  Journal of agricultural and food chemistry     Volume:  -     ISSN:  1520-5118     ISO Abbreviation:  -     Publication Date:  2011 Aug 
Date Detail:
Created Date:  2011-9-1     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0374755     Medline TA:  J Agric Food Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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