Document Detail


The new nickel tellurite chloride compound Ni(15)Te(12)O(34)Cl(10) - synthesis, crystal structure and magnetic properties.
MedLine Citation:
PMID:  23135641     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A new nickel tellurite oxohalide, Ni(15)Te(12)O(34)Cl(10), has been prepared by chemical vapour transport reactions and the crystal structure was determined by single-crystal X-ray diffraction. The compound crystallizes in the triclinic space group P1[combining macron] with the pseudomonoclinic cell parameters a = 10.3248(6) Å, b = 10.3249(6) Å, c = 11.6460(8) Å, α = 73.782(6)°, β = 73.782(6)°, γ = 63.51(2)°, Z = 1, R(1) = 0.0264. The Ni(2+) ions have octahedral [NiO(6)] and [NiO(4)Cl(2)] coordinations, the Te(4+) ions have one-sided [TeO(3)] and [TeO(4)] coordinations. The crystal structure can be described as consisting of nickel oxide ribbons extending along (001) that are connected by corner sharing [TeO(3)] and [TeO(4)] groups to build the open framework structure. The chlorine atoms and the Te-lone pairs are facing voids in the oxide framework. The new compound undergoes two successive antiferromagnetic ordering transitions at ∼50 K and ∼10 K. The Curie-Weiss temperature obtained from detailed evaluation of the high-temperature magnetic susceptibilities is positive indicating predominant ferromagnetic superexchange interactions between the Ni magnetic moments.
Authors:
Dong Zhang; Mats Johnsson; Sven Lidin; Reinhard K Kremer
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-8
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-8     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education)/College of Physics, Jilin University, Changchun 130012, P. R. China. dongzhang@jlu.edu.cn.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Interaction of l-cysteine with naked gold nanoparticles supported on HOPG: a high resolution XPS inv...
Next Document:  Five-year retrospective review of safety, injected volumes, and longevity of the hyaluronic Acid bel...