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A new chemiluminescence reagent for the determination of ruthenium.
MedLine Citation:
PMID:  18965987     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
A new reagent proflavine-N, N, N', N'-tetraacetic acid (PTA) synthesized in our laboratory has been found useful as a chemiluminescence reagent for the determination of ruthenium (Ru) in pH 2.5 sulfuric acid solution containing acetone, it can be oxidized catalytically by hydrogen peroxide. With Ru(III) as catalyst, it emits light selectively. The linear range is between 2.0 x 10(-8) and 2.0 x 10(-5) g/ml. The detection limit and the recovery rate of the method are 1.0 x 10(-9)g/ml and 96.0-102%, respectively. The method has been satisfactorily applied to determine trace Ru(III) in synthesized sample.
Authors:
Z He; Q Luo; H Ma; X Yu; Y Zeng
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Talanta     Volume:  41     ISSN:  0039-9140     ISO Abbreviation:  Talanta     Publication Date:  1994 May 
Date Detail:
Created Date:  2008-10-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2984816R     Medline TA:  Talanta     Country:  England    
Other Details:
Languages:  eng     Pagination:  707-10     Citation Subset:  -    
Affiliation:
Department of Chemistry, Wuhan University, Hubei, 430072, China.
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