Document Detail


A new approach to internal Lewis pairs featuring a phosphenium acid and a pyridine base.
MedLine Citation:
PMID:  20967330     Owner:  NLM     Status:  In-Process    
Abstract/OtherAbstract:
A bis(imino)acenaphthene (BIAN) ligand containing a pendant Lewis base has been used as a new framework to support a N-heterocyclic phosphenium cation (NHP). Reactivity studies demonstrate the ability of the ligand to act as a Lewis base, while the phosphorus centre provides a Lewis acidic site, giving new opportunities in NHP chemistry.
Authors:
Allison L Brazeau; Christine A Caputo; Caleb D Martin; Nathan D Jones; Paul J Ragogna
Publication Detail:
Type:  Journal Article     Date:  2010-10-21
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  39     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2010 Dec 
Date Detail:
Created Date:  2010-11-10     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  England    
Other Details:
Languages:  eng     Pagination:  11069-73     Citation Subset:  -    
Affiliation:
Department of Chemistry, The University of Western Ontario, 1151 Richmond St., London, ON N6A 5B7, Canada.
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