| A new approach to internal Lewis pairs featuring a phosphenium acid and a pyridine base. | |
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MedLine Citation:
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PMID: 20967330 Owner: NLM Status: In-Process |
Abstract/OtherAbstract:
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A bis(imino)acenaphthene (BIAN) ligand containing a pendant Lewis base has been used as a new framework to support a N-heterocyclic phosphenium cation (NHP). Reactivity studies demonstrate the ability of the ligand to act as a Lewis base, while the phosphorus centre provides a Lewis acidic site, giving new opportunities in NHP chemistry. |
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Authors:
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Allison L Brazeau; Christine A Caputo; Caleb D Martin; Nathan D Jones; Paul J Ragogna |
Publication Detail:
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Type: Journal Article Date: 2010-10-21 |
Journal Detail:
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Title: Dalton transactions (Cambridge, England : 2003) Volume: 39 ISSN: 1477-9234 ISO Abbreviation: Dalton Trans Publication Date: 2010 Dec |
Date Detail:
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Created Date: 2010-11-10 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101176026 Medline TA: Dalton Trans Country: England |
Other Details:
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Languages: eng Pagination: 11069-73 Citation Subset: - |
Affiliation:
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Department of Chemistry, The University of Western Ontario, 1151 Richmond St., London, ON N6A 5B7, Canada. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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