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l-Nipecotic Acid-Porphyrin Derivative: A Chiral Host with Introverted Functionality for Chiral Recognition.
MedLine Citation:
PMID:  22770121     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The synthesis and chiral recognition properties of a porphyrin host with introverted functionality is reported. The host is a hybrid of tetraphenyl zinc porphyrin and the N-phenylamide derivative of (S)-nipecotic acid. The chiral recognition properties of the porphyrin host with chiral carboxylate-containing guests is described. UV/vis and (1)H NMR spectroscopic results indicate the host shows enantioselectivity for (S)-mandelate tetrabutyl ammonium salt.
Authors:
Xiaowen Wu; Stephen D Starnes
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-7-9
Journal Detail:
Title:  Organic letters     Volume:  -     ISSN:  1523-7052     ISO Abbreviation:  -     Publication Date:  2012 Jul 
Date Detail:
Created Date:  2012-7-9     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, Texas A&M University-Commerce , Commerce, Texas 75429, United States.
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