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An improvement in the theory of regular solutions.
MedLine Citation:
PMID:  16592728     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
In constructing the theory of regular, nonpolar, binary solutions, the partial molal energy of mixing has been expressed by the square of difference between "solubility parameters," usually evaluated by the molal energy of vaporization per cubic centimeter, (DeltaE(v)/V)(1/2) = delta, at approximately 25 degrees C. We have found, however, that liquids whose molecules contain methyl groups do not conform to these parameters; to account for their solvent power for iodine requires parameters increased in proportion to the number of methyl groups per molecule. The anomaly may be attributed to the absence of outer nonbonded electrons able to exert London attractive force between neighboring molecules. Parameters derived from solubility for iodine in both methyl-containing liquids and fluorochemicals greatly improve the predictive power of the theory of regular solutions.
Authors:
J H Hildebrand
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Proceedings of the National Academy of Sciences of the United States of America     Volume:  76     ISSN:  0027-8424     ISO Abbreviation:  Proc. Natl. Acad. Sci. U.S.A.     Publication Date:  1979 Dec 
Date Detail:
Created Date:  2010-06-29     Completed Date:  2010-06-29     Revised Date:  2010-09-14    
Medline Journal Info:
Nlm Unique ID:  7505876     Medline TA:  Proc Natl Acad Sci U S A     Country:  United States    
Other Details:
Languages:  eng     Pagination:  6040-1     Citation Subset:  -    
Affiliation:
Department of Chemistry, University of California, Berkeley, California 94720.
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