Document Detail


A highly porous metal-organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake.
MedLine Citation:
PMID:  23033252     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A highly porous metal-organic framework Cu(2)(BBCDC) (BBCDC = 9,9'-([1,1'-b[combining low line]iphenyl]-4,4'-diyl)b[combining low line]is(9H-c[combining low line]arbazole-3,6-d[combining low line]ic[combining low line]arboxylate) (DUT-49) with a specific surface area of 5476 m(2) g(-1), a pore volume of 2.91 cm(3) g(-1), a H(2) excess uptake of 80 mg g(-1) (77 K, 50 bar), a CO(2) excess uptake of 2.01 g g(-1) (298 K, 50 bar) and an exceptionally high excess methane storage capacity of 308 mg g(-1) (298 K, 110 bar) was obtained using an extended tetratopic linker.
Authors:
Ulrich Stoeck; Simon Krause; Volodymyr Bon; Irena Senkovska; Stefan Kaskel
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-3
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Dresden University of Technology, Department of Inorganic Chemistry, Bergstrasse 66, 01069 Dresden, Germany. stefan.kaskel@chemie.tu-dresden.de.
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