| The gas-phase ligand exchange reactions of cobalt and zinc acetylacetonate, hexafluoroacetylacetonate, and trifluorotrimethylacetylacetonate complexes. | |
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MedLine Citation:
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PMID: 22223325 Owner: NLM Status: In-Data-Review |
Abstract/OtherAbstract:
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The gas-phase ligand exchange reactions between Co(II) and Zn(II) complexes containing the acetylacetonate (acac), hexafluoroacetylacetonate (hfac), and trifluorotrimethylacetylacetonate (tftm) ligands were investigated using a triple quadrupole mass spectrometer. The gas-phase mixed ligand products of [Cu(acac)(tftm)](+) , [Ni(acac)(tftm)](+) , [Cu(hfac)(tftm)](+) , and [Ni(hfac)(tftm)](+) were formed following the co-sublimation of either homo-metal or hetero-metal precursors and are reported herein for the first time. The fragmentation patterns of these mixed ligand species along with those of Cu(tftm)(2) and Ni(tftm)(2) are also presented. The collision cell of the instrument was utilized to examine the gas-phase reactions between mass-selected ions and specific neutral target compounds. Copyright © 2012 John Wiley & Sons, Ltd. |
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Authors:
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Gerald O Hunter; Brian D Leskiw |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Rapid communications in mass spectrometry : RCM Volume: 26 ISSN: 1097-0231 ISO Abbreviation: Rapid Commun. Mass Spectrom. Publication Date: 2012 Feb |
Date Detail:
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Created Date: 2012-01-06 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 8802365 Medline TA: Rapid Commun Mass Spectrom Country: England |
Other Details:
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Languages: eng Pagination: 369-76 Citation Subset: IM |
Copyright Information:
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Copyright © 2012 John Wiley & Sons, Ltd. |
Affiliation:
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Department of Chemistry, Youngstown State University, Youngstown, OH, 44555, USA. |
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