| A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands. | |
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MedLine Citation:
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PMID: 23147405 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Addition of [Mo(2)(V)O(2)(μ-O)(μ-S)(aq)](2+) linker-type units to a solution/dynamic library containing tungstates results via the formation of the complementary pentagonal {(W)W(5)} units logically in the self-assembly of a mixed oxide/sulphide {W(VI)(72)Mo(V)(60)}-type Keplerate, thereby demonstrating the ability to tune the capsule's skeletal softness (the (μ-O)(2) and (μ-S)(2) scenarios are known) and providing options to influence differently important capsule-substrate interactions. |
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Authors:
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Christian Schäffer; Ana Maria Todea; Hartmut Bögge; Sébastien Floquet; Emmanuel Cadot; Vladimir S Korenev; Vladimir P Fedin; Pierre Gouzerh; Achim Müller |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-11-12 |
Journal Detail:
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Title: Dalton transactions (Cambridge, England : 2003) Volume: - ISSN: 1477-9234 ISO Abbreviation: Dalton Trans Publication Date: 2012 Nov |
Date Detail:
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Created Date: 2012-11-13 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101176026 Medline TA: Dalton Trans Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Fakultät für Chemie, Universität Bielefeld, Postfach 100131, 33501 Bielefeld, Germany. a.mueller@uni-bielefeld.de. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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