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A functional graphene oxide-ionic liquid composites-gold nanoparticle sensing platform for ultrasensitive electrochemical detection of Hg(2+).
MedLine Citation:
PMID:  23314195     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A simple and sensitive electrochemical assay strategy of stripping voltammetry for mercury ions (Hg(2+)) detection is described based on the synergistic effect between ionic liquid functionalized graphene oxide (GO-IL) and gold nanoparticles (AuNPs). The AuNPs-GO-IL modified onto glassy carbon electrode (GCE) resulted in highly enhanced electron conductive nanostructured membrane and large electroactive surface area, which was excellently examined by scanning electron microscopy and cyclic voltammetry. After accumulating Hg(2+), anodic stripping voltammetry (ASV) was performed, and differential pulse voltammetry (DPV) was employed for signal recording of Hg(2+). Several main experimental parameters were optimized, i.e., deposition potential and time of AuNPs were -0.2 V and 180 s, respectively, and accumulation potential and time of Hg(2+) were -0.3 V and 660 s, respectively. Under the optimal conditions, this AuNPs-GO-IL-GCE sensor attained a good linearity in a wide range of 0.1-100 nM (R = 0.9808) between the concentration of the Hg(2+) standard and peak current. The limit of detection was estimated to be 0.03 nM at a signal-to-noise ratio of 3σ. A variety of common coexistent ions in water samples were investigated, showing no obvious interferences on the Hg(2+) detection. The practical application of the proposed sensor has been carried out and demonstrated as feasible for determination of trace levels of Hg(2+) in drinking and environmental water samples.
Authors:
Na Zhou; Jinhua Li; Hao Chen; Chunyang Liao; Lingxin Chen
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-14
Journal Detail:
Title:  The Analyst     Volume:  -     ISSN:  1364-5528     ISO Abbreviation:  Analyst     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0372652     Medline TA:  Analyst     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, China. lxchen@yic.ac.cn.
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