Document Detail


The formation and stability of molybdenum-antimony and tungsten-antimony ternary oxides Sb(2)MO(6), Sb(2)M(2)O(9), Sb(2)Mo(3)O(12) and Sb(4)MO(9) in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies.
MedLine Citation:
PMID:  22850648     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The ternary oxides Sb(2)MO(6), Sb(2)M(2)O(9), Sb(4)MO(9) (M = Mo, W) and Sb(2)Mo(3)O(12) were detected in the gas phase by means of mass spectrometry (MS). These gaseous oxides are reported for the first time. Thermodynamic data was obtained experimentally and confirmed by quantum chemical (QC) calculations. In addition, structural data on these molecules was obtained. The ionisation potentials (IP) were also determined both experimentally and theoretically.
Authors:
E Berezovskaya; E Milke; M Binnewies
Related Documents :
16970428 - Metallic single-crystal cosi nanowires via chemical vapor deposition of single-source p...
20355658 - Fabrication of nano-hydroxyapatite using a novel ultrasonic atomization precipitation m...
19435048 - Fabrication of dendrimer porogen-capsulated mesoporous silica via sol-gel process of si...
20877888 - Chemical redox-regulated mesoporous silica-coated gold nanorods for colorimetric probin...
3601658 - Oligodeoxyribonucleoside methylphosphonates. nmr and uv spectroscopic studies of rp-rp ...
17212508 - Density functional investigation of the interaction of acetone with small gold clusters.
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-7-31
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 Jul 
Date Detail:
Created Date:  2012-8-1     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Institut für Anorganische Chemie, Leibniz Universität Hannover, Callinstr. 9, 30167 Hannover, Germany. katja.berezovskaya@aca.uni-hannover.de.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Data on Wistar Hannover rats from a general toxicity study.
Next Document:  Estimation of Maximal Oxygen Uptake without Exercise Testing in Korean Healthy Adult Workers.