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The formation and stability of molybdenum-antimony and tungsten-antimony ternary oxides Sb(2)MO(6), Sb(2)M(2)O(9), Sb(2)Mo(3)O(12) and Sb(4)MO(9) in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies.
MedLine Citation:
PMID:  22850648     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The ternary oxides Sb(2)MO(6), Sb(2)M(2)O(9), Sb(4)MO(9) (M = Mo, W) and Sb(2)Mo(3)O(12) were detected in the gas phase by means of mass spectrometry (MS). These gaseous oxides are reported for the first time. Thermodynamic data was obtained experimentally and confirmed by quantum chemical (QC) calculations. In addition, structural data on these molecules was obtained. The ionisation potentials (IP) were also determined both experimentally and theoretically.
Authors:
E Berezovskaya; E Milke; M Binnewies
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-7-31
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 Jul 
Date Detail:
Created Date:  2012-8-1     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Institut für Anorganische Chemie, Leibniz Universität Hannover, Callinstr. 9, 30167 Hannover, Germany. katja.berezovskaya@aca.uni-hannover.de.
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