Document Detail


An efficient preparation of polyanionic affinity agent and its evaluation for the measurement of glycated hemoglobin.
MedLine Citation:
PMID:  15848760     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
An efficient method was developed for the preparation of polyanionic affinity agent (3), a key component in the measurement of glycated hemoglobin (GHb). Glycated hemoglobin is an important clinical marker for diagnosis of patients with diabetes and useful to monitor the management of disease. The affinity agent (3) was prepared based on coupling reaction between poly(acrylic acid) (1) and 3-aminophenylboronic acid (2) in water. The critical features of this polymeric affinity agent (3), such as size, boronic acid incorporation ratio and concentration, on the measurement of glycated hemoglobin were evaluated. It was found that the agent (3) prepared using poly(acrylic acid) (1) with 225 kDa molecular weight gave optimal GHb measurement. The performance test results demonstrated that the boronic acid incorporation ratio and concentration of affinity agent (3) play a critical role in the assay and determines the precision of glycated hemoglobin measurement.
Authors:
Rajarathnam E Reddy; You Pan; Donald D Johnson; Yon-Yih Chen; Saul A Datwyler; Michelle S Hauptman; John K Thottathil
Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Bioorganic & medicinal chemistry     Volume:  13     ISSN:  0968-0896     ISO Abbreviation:  Bioorg. Med. Chem.     Publication Date:  2005 May 
Date Detail:
Created Date:  2005-04-25     Completed Date:  2005-09-08     Revised Date:  2007-11-15    
Medline Journal Info:
Nlm Unique ID:  9413298     Medline TA:  Bioorg Med Chem     Country:  England    
Other Details:
Languages:  eng     Pagination:  3467-73     Citation Subset:  IM    
Affiliation:
Core R&D Chemistry Group, (Dept: 09MD, Bldg: AP20), Diagnostics Division, Abbott Laboratories, 100 Abbott Park Road, Abbott Park, IL 60064-6016, USA. rajarathnam.reddy@abbott.com
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MeSH Terms
Descriptor/Qualifier:
Acrylic Resins / chemical synthesis*,  chemistry,  metabolism
Boronic Acids / chemical synthesis*,  chemistry,  metabolism
Chromatography, Affinity
Evaluation Studies as Topic
Hemoglobin A, Glycosylated / analysis*,  metabolism*
Humans
Chemical
Reg. No./Substance:
0/Acrylic Resins; 0/Boronic Acids; 0/Hemoglobin A, Glycosylated; 30418-59-8/3-aminobenzeneboronic acid; 9003-01-4/carbopol 940

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