Document Detail


An eco-friendly N-sulfonylation of amines using stable and reusable Zn-Al-hydrotalcite solid base catalyst under ultrasound irradiation.
MedLine Citation:
PMID:  20627793     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Synthetic nanosized Zn-Al-hydrotalcite (Zn-Al-HT) with 20 nm crystallite size and 61 m(2)/g BET-surface area is found to be a mild and efficient catalyst for N-sulfonylation of amines in quantitative yields under ultrasound irradiation. Exclusive synthesis of sulfonamides, using Zn-Al-HT, under ultrasound irradiation, was realized by compatible basic sites of catalyst used. The products were isolated after simple work-up in high yields and purity.
Authors:
M Mokhtar; T S Saleh; N S Ahmed; S A Al-Thabaiti; R A Al-Shareef
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Publication Detail:
Type:  Journal Article     Date:  2010-05-10
Journal Detail:
Title:  Ultrasonics sonochemistry     Volume:  18     ISSN:  1873-2828     ISO Abbreviation:  Ultrason Sonochem     Publication Date:  2011 Jan 
Date Detail:
Created Date:  2010-09-13     Completed Date:  2011-01-13     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9433356     Medline TA:  Ultrason Sonochem     Country:  Netherlands    
Other Details:
Languages:  eng     Pagination:  172-6     Citation Subset:  IM    
Copyright Information:
Copyright © 2010 Elsevier B.V. All rights reserved.
Affiliation:
Chemistry Department, Faculty of Science, King Abdulaziz University, 21589 Jeddah, P.O. Box 80203, Saudi Arabia.
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MeSH Terms
Descriptor/Qualifier:
Aluminum / chemistry*
Aluminum Hydroxide / chemistry*
Amines / chemistry*
Catalysis
Magnesium Hydroxide / chemistry*
Nanoparticles / chemistry
Particle Size
Sulfonic Acids / chemistry*
Surface Properties
Ultrasonics*
Zinc / chemistry*
Chemical
Reg. No./Substance:
0/Amines; 0/Sulfonic Acids; 12304-65-3/hydrotalcite; 1309-42-8/Magnesium Hydroxide; 21645-51-2/Aluminum Hydroxide; 7429-90-5/Aluminum; 7440-66-6/Zinc

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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