Document Detail


The early events in the OH radical oxidation of dimethyl sulfide in water.
MedLine Citation:
PMID:  23387604     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
The time-resolved Raman observation of a prototype of the hetero-atom three electron bonds (-X-OH) that often form on encounter of the OH radical with chemical species in water is reported. In spite of their wide chemical and biochemical importance, no experimental structural information exists, thus far, on any such bond in solution or in the gas phase. The nature of the >S-O bond formed on the reaction of the OH radical with dimethyl sulfide in water, investigated in the present work, would necessitate a reexamination of the existing reaction mechanisms in related biological systems and development of the appropriate computational methods.
Authors:
Ireneusz Janik; G N R Tripathi
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  The Journal of chemical physics     Volume:  138     ISSN:  1089-7690     ISO Abbreviation:  J Chem Phys     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-02-07     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0375360     Medline TA:  J Chem Phys     Country:  United States    
Other Details:
Languages:  eng     Pagination:  044506     Citation Subset:  IM    
Affiliation:
Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556, USA.
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