Document Detail


The dimerization of delta-1-piperidine-2-carboxylic acid.
MedLine Citation:
PMID:  5584009     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
The l-amino acid oxidase of Mytilus edulis has been used to oxidize l-lysine on a large scale in the presence of catalase. The alpha-oxo acid derived from lysine cyclizes to a Schiff base, which readily dimerizes. The dimer undergoes spontaneous dehydration and decarboxylation to form 1,2,3,4,5,6,7,8-octahydropyrido[3,2-a]-indolizin-10(4bH)-one. This structure was established by a study of its molecular weight and infrared, nuclear-magnetic-resonance and mass spectra.
Authors:
D B Hope; K C Horncastle; R T Aplin
Related Documents :
11672739 - A basic peroxidase from wheat kernel with antifungal activity.
8837739 - Effects of steric bulk and conformational rigidity on fatty acid omega hydroxylation by...
17841979 - Differential enzymatic activity in ecological races of typha latifolia l.
7319 - Oxidation of sarcosine and n-alkyl derivatives of glycine by d-amino-acid oxidase.
12782459 - Determination of d- and l-alanine concentrations using a pyruvic acid sensor.
8074299 - Determination of manganese peroxidase activity with 3-methyl-2-benzothiazolinone hydraz...
12053989 - Comparison of nodulisporic acid analogs in a lucilia sericata in vitro assay and a cten...
2770059 - Effects of diltiazem on plasma uric acid level and renal uric acid excretion in rats.
16308269 - Increased serum bile acids as a possible biomarker of hepatotoxicity in brazilian worke...
Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  The Biochemical journal     Volume:  105     ISSN:  0264-6021     ISO Abbreviation:  Biochem. J.     Publication Date:  1967 Nov 
Date Detail:
Created Date:  1968-06-03     Completed Date:  1968-06-03     Revised Date:  2010-09-13    
Medline Journal Info:
Nlm Unique ID:  2984726R     Medline TA:  Biochem J     Country:  ENGLAND    
Other Details:
Languages:  eng     Pagination:  663-7     Citation Subset:  IM    
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:
Amino Acid Oxidoreductases*
Animals
Catalase
Chemistry, Physical
Lysine
Magnetic Resonance Spectroscopy
Manometry
Models, Chemical
Molecular Weight
Mollusca / enzymology*
Physicochemical Phenomena
Piperidines*
Spectrophotometry
Spectrum Analysis
Chemical
Reg. No./Substance:
0/Piperidines; 56-87-1/Lysine; EC 1.11.1.6/Catalase; EC 1.4.-/Amino Acid Oxidoreductases
Comments/Corrections

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Enzymic glucosylation of phenols.
Next Document:  The hydrolysis of glycosyl fluorides by glycosidases.