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A copper thiolate centre for electron transfer: mononuclear vs. dinuclear complexes.
MedLine Citation:
PMID:  22314404     Owner:  NLM     Status:  Publisher    
We have structurally and spectroscopically investigated a rare example of a mononuclear aliphatic dithiolate Cu(II) complex characterized by a reversible Cu(II)/Cu(I) redox couple. By DFT, we have shown that this system has a lower reorganization energy than its previously described bis(μ-thiolato) dicopper parent complex, which reversibly cycles between the Cu(1.5)Cu(1.5) and Cu(I)Cu(I) redox states.
Marcello Gennari; Jacques Pécaut; Marie-Noëlle Collomb; Carole Duboc
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-2-8
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  -     Publication Date:  2012 Feb 
Date Detail:
Created Date:  2012-2-8     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Université Joseph Fourier Grenoble 1/CNRS, Département de Chimie Moléculaire, UMR-5250, Institut de Chimie Moléculaire de Grenoble FR- CNRS-2607, BP-53, 38041, Grenoble Cedex 9, France.
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