| A copper thiolate centre for electron transfer: mononuclear vs. dinuclear complexes. | |
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MedLine Citation:
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PMID: 22314404 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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We have structurally and spectroscopically investigated a rare example of a mononuclear aliphatic dithiolate Cu(II) complex characterized by a reversible Cu(II)/Cu(I) redox couple. By DFT, we have shown that this system has a lower reorganization energy than its previously described bis(μ-thiolato) dicopper parent complex, which reversibly cycles between the Cu(1.5)Cu(1.5) and Cu(I)Cu(I) redox states. |
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Authors:
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Marcello Gennari; Jacques Pécaut; Marie-Noëlle Collomb; Carole Duboc |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-2-8 |
Journal Detail:
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Title: Dalton transactions (Cambridge, England : 2003) Volume: - ISSN: 1477-9234 ISO Abbreviation: - Publication Date: 2012 Feb |
Date Detail:
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Created Date: 2012-2-8 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101176026 Medline TA: Dalton Trans Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Université Joseph Fourier Grenoble 1/CNRS, Département de Chimie Moléculaire, UMR-5250, Institut de Chimie Moléculaire de Grenoble FR- CNRS-2607, BP-53, 38041, Grenoble Cedex 9, France. carole.duboc@ujf-grenoble.fr. |
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