Document Detail


A continuous process for biodiesel production in a fixed bed reactor packed with cation-exchange resin as heterogeneous catalyst.
MedLine Citation:
PMID:  21078550     Owner:  NLM     Status:  In-Process    
Abstract/OtherAbstract:
Continuous esterification of free fatty acids (FFA) from acidified oil with methanol was carried out with NKC-9 cation-exchange resin in a fixed bed reactor with an internal diameter of 25 mm and a height of 450 mm to produce biodiesel. The results showed that the FFA conversion increased with increases in methanol/oil mass ratio, reaction temperature and catalyst bed height, whereas decreased with increases in initial water content in feedstock and feed flow rate. The FFA conversion kept over 98.0% during 500 h of continuous esterification processes under 2.8:1 methanol to oleic acid mass ratio, 44.0 cm catalyst bed height, 0.62 ml/min feed flow rate and 65°C reaction temperature, showing a much high conversion and operational stability. Furthermore, the loss of sulfonic acid groups from NKC-9 resin into the production was not found during continuous esterification. In sum, NKC-9 resin shows the potential commercial applications to esterification of FFA.
Authors:
Yaohui Feng; Aiqing Zhang; Jianxin Li; Benqiao He
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2010-10-28
Journal Detail:
Title:  Bioresource technology     Volume:  102     ISSN:  1873-2976     ISO Abbreviation:  Bioresour. Technol.     Publication Date:  2011 Feb 
Date Detail:
Created Date:  2011-01-10     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9889523     Medline TA:  Bioresour Technol     Country:  England    
Other Details:
Languages:  eng     Pagination:  3607-9     Citation Subset:  IM    
Copyright Information:
Copyright © 2010 Elsevier Ltd. All rights reserved.
Affiliation:
The State Key Lab of Hollow Fiber Membrane Materials and Processes, School of Material and Chemical Engineering, Tianjin Polytechnic University, Tianjin, PR China.
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