Document Detail


An autocatalytic radical chain pathway in formation of an iron(iv)-oxo complex by oxidation of an iron(ii) complex with dioxygen and isopropanol.
MedLine Citation:
PMID:  23423328     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Evidence of an autocatalytic radical chain pathway has been reported in formation of a non-heme iron(iv)-oxo complex by oxidation of an iron(ii) complex with dioxygen and isopropanol in acetonitrile at 298 K. The radical chain reaction is initiated by hydrogen abstraction from isopropanol by the iron(iv)-oxo complex.
Authors:
Yuma Morimoto; Yong-Min Lee; Wonwoo Nam; Shunichi Fukuzumi
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-2-20
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Feb 
Date Detail:
Created Date:  2013-2-20     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Material and Life Science, Graduate School of Engineering, Osaka University and ALCA (JST), 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan. fukuzumi@chem.eng.osaka-u.ac.jp.
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