Document Detail


An arene-stabilized cobalt(I) aryl: reactions with CO and NO.
MedLine Citation:
PMID:  18855383     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
The half-sandwich cobalt(I) complex (eta (6)-C 7H 8)CoAr*-3,5- ( i )Pr 2 (Ar*-3,5- ( i )Pr 2 = -C 6H-2,6-(C 6H 2-2,4,6- ( i )Pr 3) 2-3,5- ( i )Pr 2) was synthesized by reduction of [3,5- ( i )Pr 2Ar*Co(mu-Cl)] 2 in toluene. It reacts with CO or NO to afford the unusual complexes [3,5- ( i )Pr 2Ar*C(O)Co(CO)] or [3,5- ( i )Pr 2Ar*N(NO)OCo(NO) 2].
Authors:
Hao Lei; Bobby D Ellis; Chengbao Ni; Fernande Grandjean; Gary J Long; Philip P Power
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Publication Detail:
Type:  Journal Article     Date:  2008-10-15
Journal Detail:
Title:  Inorganic chemistry     Volume:  47     ISSN:  1520-510X     ISO Abbreviation:  Inorg Chem     Publication Date:  2008 Nov 
Date Detail:
Created Date:  2008-11-10     Completed Date:  2008-12-02     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0366543     Medline TA:  Inorg Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  10205-7     Citation Subset:  -    
Affiliation:
Department of Chemistry, University of California, Davis, California 95616, USA.
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