| An arene-stabilized cobalt(I) aryl: reactions with CO and NO. | |
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MedLine Citation:
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PMID: 18855383 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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The half-sandwich cobalt(I) complex (eta (6)-C 7H 8)CoAr*-3,5- ( i )Pr 2 (Ar*-3,5- ( i )Pr 2 = -C 6H-2,6-(C 6H 2-2,4,6- ( i )Pr 3) 2-3,5- ( i )Pr 2) was synthesized by reduction of [3,5- ( i )Pr 2Ar*Co(mu-Cl)] 2 in toluene. It reacts with CO or NO to afford the unusual complexes [3,5- ( i )Pr 2Ar*C(O)Co(CO)] or [3,5- ( i )Pr 2Ar*N(NO)OCo(NO) 2]. |
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Authors:
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Hao Lei; Bobby D Ellis; Chengbao Ni; Fernande Grandjean; Gary J Long; Philip P Power |
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Publication Detail:
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Type: Journal Article Date: 2008-10-15 |
Journal Detail:
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Title: Inorganic chemistry Volume: 47 ISSN: 1520-510X ISO Abbreviation: Inorg Chem Publication Date: 2008 Nov |
Date Detail:
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Created Date: 2008-11-10 Completed Date: 2008-12-02 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0366543 Medline TA: Inorg Chem Country: United States |
Other Details:
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Languages: eng Pagination: 10205-7 Citation Subset: - |
Affiliation:
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Department of Chemistry, University of California, Davis, California 95616, USA. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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