Document Detail


Work fluctuations in an elastic dumbbell model of polymers in planar elongational flow.
MedLine Citation:
PMID:  21599196     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
We use a path-integral approach to calculate the distribution P(w,t) of the fluctuations in the work w at time t of a polymer molecule (modeled as an elastic dumbbell in a viscous solvent) that is acted on by an elongational flow field having a flow rate γ̇. We find thatP(w,t) is non-Gaussian and that, at long times, the ratio P(w,t)/P(-w,t) is equal to exp[w/(k_{B}T)], independent of γ̇. On the basis of this finding, we suggest that polymers in elongational flows satisfy a fluctuation theorem.
Authors:
Rati Sharma; Binny J Cherayil
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-4-28
Journal Detail:
Title:  Physical review. E, Statistical, nonlinear, and soft matter physics     Volume:  83     ISSN:  1550-2376     ISO Abbreviation:  -     Publication Date:  2011 Apr 
Date Detail:
Created Date:  2011-5-23     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101136452     Medline TA:  Phys Rev E Stat Nonlin Soft Matter Phys     Country:  -    
Other Details:
Languages:  ENG     Pagination:  041805     Citation Subset:  -    
Affiliation:
Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore-560012, India.
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