Document Detail

Why Condensate Drops Can Spontaneously Move Away on Some Superhydrophobic Surfaces but Can not on others?
MedLine Citation:
PMID:  23153202     Owner:  NLM     Status:  Publisher    
The coalesce-induced condensate drop motion on some superhydrophobic surfaces (SHSs) has attracted increasing attention due to its wide potential applications. However, microscopic mechanism of spontaneous motion has not been discussed thoroughly. In this study, we fabricated two types of superhydrophobic copper surfaces with sisal-like nanoribbon structures and defoliation-like nanosheet structures by different wet chemical oxidation process and followed by same fluorization treatment. With lotus leaf and butterfly wing as control samples, the spontaneous motion phenomenon of condensate drops on these four kinds of SHSs was investigated by using optical microscope under ambient conditions. The results showed that among all four types of SHSs, only superhydrophobic copper surfaces with sisal-like nanoribbon structures showed obvious spontaneous motion of condensate drops, especially when the relative humidity was higher. The microscopic mechanism of spontaneous motion was discussed in relation to the states of condensate drops on different nanostructures. It shows that the instantaneous Cassie state of condensed droplets prior to coalescence plays a key role in determining whether the coalesced drop departs while only SHS possessing nanostructures with small enough Wenzel roughness parameter r (at least less than 2.1) and nanogaps forming high enough Laplace pressure that favors the formation of the instantaneous Cassie state by completing the Wenzel-Cassie transition.
Jie Feng; Yichuan Pang; Zhaoqian Qin; Ruiyuan Ma; Shuhuai Yao
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-16
Journal Detail:
Title:  ACS applied materials & interfaces     Volume:  -     ISSN:  1944-8252     ISO Abbreviation:  ACS Appl Mater Interfaces     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-16     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101504991     Medline TA:  ACS Appl Mater Interfaces     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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