Document Detail


Well-Organized CdS/C(60) in Block Copolymer Micellar Cores.
MedLine Citation:
PMID:  21706557     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
CdS nanoparticles of 4.5 nm diameter were synthesized in poly(2-vinylpyridine) micellar cores which were obtained by solvating a polystyrene-block-poly(2-vinylpyridine) block copolymer in polystyrene-selective toluene. Then, a C(60) -toluene solution was dispersed into the CdS micelle solution with stirring. This led to the well-defined organization of two different nanoparticles; specifically: a CdS NP decorated by several/dozens of C(60) molecules, because C(60) molecules were strongly coordinated with pyridine molecules in the micellar cores by charge-transfer complexation C 60δ--P2VP(δ+) . A harmoniously organized CdS/C(60) micellar structure was clearly verified by transmission electron microscopy. Fluorescent quenching of CdS nanoparticles, which was strongly affected by neighboring C(60) molecules, was observed.
Authors:
Haeng-Deog Koh; Jung-Pil Lee; Jae-Suk Lee
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Publication Detail:
Type:  Journal Article     Date:  2009-04-21
Journal Detail:
Title:  Macromolecular rapid communications     Volume:  30     ISSN:  1022-1336     ISO Abbreviation:  Macromol Rapid Commun     Publication Date:  2009 Jun 
Date Detail:
Created Date:  2011-06-27     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9888239     Medline TA:  Macromol Rapid Commun     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  976-80     Citation Subset:  -    
Copyright Information:
Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Department of Materials Science and Engineering, Gwangju Institute of Science and Technology (GIST), 261 Cheomdan-gwagiro (Oryong-dong), Buk-gu, Gwangju 500-712, Korea.
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