Document Detail

Water structure and charge transfer phenomena at the liquid-graphene interface.
MedLine Citation:
PMID:  23019576     Owner:  NLM     Status:  Publisher    
Physicochemical properties of the graphene-water interface have been investigated to scrutinize the perturbations with respect to the graphene-air interface, in terms of changes in optical and vibrational spectra, as well as in the 3D network of water. Experimental investigations were carried out using Raman spectroscopy and laser scanning confocal microscopy, and integrated with density functional theory (DFT) calculations. Results evidence a substantial orientation of the hydrogen-bonded water molecules at the interfacial region, which, in turn, induces disorder in the water clusters and interfacial charge transfer phenomena.
Luisa D'Urso; Cristina Satriano; Giuseppe Forte; Giuseppe Compagnini; Orazio Puglisi
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-9-28
Journal Detail:
Title:  Physical chemistry chemical physics : PCCP     Volume:  -     ISSN:  1463-9084     ISO Abbreviation:  Phys Chem Chem Phys     Publication Date:  2012 Sep 
Date Detail:
Created Date:  2012-9-28     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100888160     Medline TA:  Phys Chem Chem Phys     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Department of Chemical Sciences, University of Catania, viale Andrea Doria 6, 95125, Catania, Italy.
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