Document Detail


Water quality guidance for protection of freshwater mussels (Unionidae) from ammonia exposure.
MedLine Citation:
PMID:  14587894     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Ammonia toxicity data for freshwater mussels (Unionidae), a significantly imperiled taxa, were used to derive estimates of concentrations that would not likely be harmful in acute and chronic exposures and to assess the protectiveness of current U.S. Environmental Protection Agency (U.S. EPA) water quality criteria to this family of organisms. Thirty acute (24-96-h) median lethal concentrations (LC50s), covering 10 species in eight unionid genera, were used to calculate genus mean acute values (GMAVs) ranging from 2.56 to 8.97 mg/L total ammonia as N at pH 8. Freshwater mussels are at the sensitive end of the range when added to the GMAVs from the database used to derive the U.S. EPA criteria maximum concentration (CMC). We derived two estimates of acute exposure water quality guidance for the protection of freshwater mussels (CMC(FM)) by a recalculation of the CMC after adding freshwater mussel GMAVs to the U.S. EPA data set. The CMC(FM)s of 1.75 and 2.50 mg/L total ammonia as N at pH 8 average 60% less than the U.S. EPA CMC of 5.62 mg/L total ammonia as N at pH 8 for application when salmonids are present. These values average about 75% less than the CMC for application when salmonids are absent. No chronic ammonia exposure data existed for unionids. Thus, we applied a range of estimated acute:chronic ratios to the acute toxicity data set, expanded with the freshwater mussel GMAVs. to estimate continuous ammonia concentrations that may be protective of freshwater mussels. These estimates ranged from 0.3 to 1.0 mg/L total ammonia as N at pH 8, about 20 to 75% less than the U.S. EPA criteria continuous concentration (CCC) of 1.24 mg/L total ammonia as N at pH 8 and 25 degrees C. The current numeric criteria for ammonia may not be protective of mussels, more than half of whose nearly 300 species are in decline in North America. While the CMC(FM) and CCC(FM) are not equivalent to revised U.S. EPA criteria, they are offered as interim guidance for the protection of freshwater mussels.
Authors:
Tom Augspurger; Anne E Keller; Marsha C Black; W Gregory Cope; F James Dwyer
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Environmental toxicology and chemistry / SETAC     Volume:  22     ISSN:  0730-7268     ISO Abbreviation:  Environ. Toxicol. Chem.     Publication Date:  2003 Nov 
Date Detail:
Created Date:  2003-10-31     Completed Date:  2004-02-10     Revised Date:  2007-11-15    
Medline Journal Info:
Nlm Unique ID:  8308958     Medline TA:  Environ Toxicol Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  2569-75     Citation Subset:  IM    
Affiliation:
U.S. Fish and Wildlife Service, P.O. Box 33726, Raleigh, North Carolina 27636-3726, USA. tom_augspurger@fws.gov
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MeSH Terms
Descriptor/Qualifier:
Ammonia / standards*,  toxicity*
Animals
Bivalvia*
Conservation of Natural Resources*
Environment*
Guidelines as Topic*
Hydrogen-Ion Concentration
Lethal Dose 50
Risk Assessment
United States
United States Environmental Protection Agency
Water Pollutants / standards*,  toxicity*
Chemical
Reg. No./Substance:
0/Water Pollutants; 7664-41-7/Ammonia

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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