Document Detail


"Visible Light Mediated Utilization of α-Aminoalkyl Radicals: Addition to Electron Deficient Alkenes Using Photoredox Catalysts.
MedLine Citation:
PMID:  22296639     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Synthetic utilization of α-aminoalkyl radicals formed by a single electron oxidation of amines is quite limited. Here, we demonstrate the addition of α-aminoalkyl radicals to electron deficient alkenes via visible light mediated an electron transfer process using transition metal polypyridyl complexes as photocatalysts. The reaction proceeds via a sequential redox pathway.
Authors:
Yoshihiro Miyake; Kazunari Nakajima; Yoshiaki Nishibayashi
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-1-26
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  -     ISSN:  1520-5126     ISO Abbreviation:  -     Publication Date:  2012 Jan 
Date Detail:
Created Date:  2012-2-2     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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