Document Detail


Vibrational spectroscopic study of fluticasone propionate.
MedLine Citation:
PMID:  19095495     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Fluticasone propionate is a synthetic glucocorticoid with potent anti-inflammatory activity that has been used effectively in the treatment of chronic asthma. The present work reports a vibrational spectroscopic study of fluticasone propionate and gives proposed molecular assignments on the basis of ab initio calculations using BLYP density functional theory with a 6-31G* basis set and vibrational frequencies predicted within the quasi-harmonic approximation. Several spectral features and band intensities are explained. This study generated a library of information that can be employed to aid the process monitoring of fluticasone propionate.
Authors:
H R H Ali; H G M Edwards; J Kendrick; I J Scowen
Related Documents :
9512045 - Vibrational spectrum of the lumi intermediate in the room temperature rhodopsin photo-r...
15741105 - Vibrational frequencies and structural determinations of divinyl sulfoxide.
18851235 - Ab initio finite-temperature excitons.
22621345 - Photoelectrochemical properties of tio(2) nanowire arrays: a study of the dependence on...
11536295 - Structure suggests function: the case for synaptic ribbons as exocytotic nanomachines.
19530695 - Transannular proton transfer in the cyclization of geranylgeranyl diphosphate to fusico...
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2008-11-05
Journal Detail:
Title:  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy     Volume:  72     ISSN:  1386-1425     ISO Abbreviation:  Spectrochim Acta A Mol Biomol Spectrosc     Publication Date:  2009 Mar 
Date Detail:
Created Date:  2009-01-12     Completed Date:  2009-03-16     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9602533     Medline TA:  Spectrochim Acta A Mol Biomol Spectrosc     Country:  England    
Other Details:
Languages:  eng     Pagination:  244-7     Citation Subset:  IM    
Affiliation:
School of Life Sciences, University of Bradford, Bradford, BD7 1DP, UK.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:
Androstadienes / chemistry*
Anti-Inflammatory Agents / chemistry*
Molecular Structure
Spectrum Analysis, Raman*
Vibration
Chemical
Reg. No./Substance:
0/Androstadienes; 0/Anti-Inflammatory Agents; 90566-53-3/fluticasone

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Stability of pyrene-1-carboxylic acid and other pyrene derivatives immobilized on silane gels.
Next Document:  Patterns and changes in prescriber attitudes toward PDA prescription-assistive technology.