Document Detail

Vapor-phase carbonylation of dimethoxymethane over H-Faujasite.
MedLine Citation:
PMID:  19452505     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Carbonylation gets a phase lift: The usual liquid-phase, high-pressure processes for carbonylating formaldehydes are avoided in a novel vapor-phase reaction. Using an acid zeolite (Faujasite) at near-atmospheric pressure dimethoxymethane (DMM; the dimethyl acetal of formaldehyde; see scheme) is carbonylated to produce methyl methoxyacetate (MMAc). This approach provides a new route to ethylene glycol under mild conditions.
Fuat E Celik; Tae-Jin Kim; Alexis T Bell
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  48     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2009  
Date Detail:
Created Date:  2009-06-17     Completed Date:  2009-08-31     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  4813-5     Citation Subset:  -    
Chemical Engineering, University of California, Berkeley, Berkeley, CA 94720, USA.
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