| Using alkaline-earth metal ions to tune structural variations of 1,3,5-benzenetricarboxylate coordination polymers. | |
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MedLine Citation:
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PMID: 23154614 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Alkaline-earth metal ions were used to tune four new heterometallic frameworks, {[Cd(2.07)Mg(0.93)(BTC)(2)(H(2)O)(4)]·2H(2)O}(n) (), {[Cd(2)Ca(BTC)(2)(H(2)O)(4)]·2H(2)O}(n) (), {[Cd(2)Sr(BTC)(2)(H(2)O)(5)]·H(2)O}(n) () and [Cd(6)Ba(3)(BTC)(3)(H(2)O)(10)](n) () (H(3)BTC = 1,3,5-benzenetricarboxylic acid), synthesized from H(3)BTC and the corresponding metal salts. Single-crystal X-ray analysis shows that compound is a three-dimensional (3D) framework based on heterometallic Cd-O-Cd-O-Mg inorganic chain subunits, compounds and are basically isostructural and feature a 3D framework based on Ca(ii) or Sr(ii) polyhedrons decorated with Cd-O-Cd inorganic chains. Compound is a 3D framework templated by disordered inorganic hydrate Ba(ii) ions, and also features inorganic Cd-O-Cd chains, which are connected together through corner sharing with the {Cd(1)O(6)} polyhedrons by {Ba(1)O(6)} polyhedrons, giving rise to a rare heterometallic 3D inorganic skeleton. Moreover, the solid-state fluorescence of compounds and NLO properties of compounds have also been investigated at room temperature. |
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Authors:
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Xin Zhang; Yuan-Yuan Huang; Qi-Pu Lin; Jian Zhang; Yuan-Gen Yao |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-11-15 |
Journal Detail:
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Title: Dalton transactions (Cambridge, England : 2003) Volume: - ISSN: 1477-9234 ISO Abbreviation: Dalton Trans Publication Date: 2012 Nov |
Date Detail:
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Created Date: 2012-11-16 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101176026 Medline TA: Dalton Trans Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Key Laboratory of Coal to Ethylene Glycol and its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China. yyg@fjirsm.ac.cn. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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