Document Detail


Use of high performance liquid chromatography in defining the abnormalities in the free amino acid patterns in the cerebrospinal fluid of patients with aseptic meningitis.
MedLine Citation:
PMID:  1683804     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Free amino acids were quantitatively determined in cerebrospinal fluid (CSF) and plasma samples from patients with aseptic meningitis by a newly developed high performance liquid chromatographic (HPLC) method. The method of analysis was based on precolumn derivatization of orthophthaladehyde in the presence of 2-mercaptoethanol and detection was made at Eex = 340 nm and Eem = 450 nm. The method was sensitive and the limit for detection was less than 1 pmol for most of the amino acids. It took 45 min to separate 26 amino acids with highly reproducible results, giving a coefficient of variance for retention times and integrated areas less than 0.4% and 2%, respectively, after five replicate runs. The results accumulated in 10 patients were compared statistically with 11 age-matched healthy controls. Among the amino acids almost all the neurotransmitter candidates, such as aspartic acid, glutamic acid, glutamine, glycine, tyrosine, phenylalanine and gamma-aminobutyric acid (GABA), were significantly increased in the patients' CSF, whereas arginine and threonine were low. No change was observed in plasma amino acids in patients as compared to healthy controls. The higher levels of most of the neurotransmitters, especially GABA, aspartic acid and glutamic acid, could be used diagnostically in assessing the progression and remission in aseptic meningitis.
Authors:
I Halawa; S Baig; G A Qureshi
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Biomedical chromatography : BMC     Volume:  5     ISSN:  0269-3879     ISO Abbreviation:  Biomed. Chromatogr.     Publication Date:  1991 Sep 
Date Detail:
Created Date:  1992-01-14     Completed Date:  1992-01-14     Revised Date:  2004-11-17    
Medline Journal Info:
Nlm Unique ID:  8610241     Medline TA:  Biomed Chromatogr     Country:  ENGLAND    
Other Details:
Languages:  eng     Pagination:  216-20     Citation Subset:  IM    
Affiliation:
Department of Neurology, Karolinska Institute, Huddinge University Hospital, Stockholm, Sweden.
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MeSH Terms
Descriptor/Qualifier:
Adult
Aged
Amino Acids / blood,  cerebrospinal fluid*
Aspartic Acid / blood,  cerebrospinal fluid
Chromatography, High Pressure Liquid / methods*
Female
Glutamates / blood,  cerebrospinal fluid
Glutamic Acid
Glycine / blood,  cerebrospinal fluid
Humans
Male
Meningitis, Aseptic / blood,  cerebrospinal fluid*
Middle Aged
Phenylalanine / blood,  cerebrospinal fluid
Tyrosine / blood,  cerebrospinal fluid
gamma-Aminobutyric Acid / blood,  cerebrospinal fluid
Chemical
Reg. No./Substance:
0/Amino Acids; 0/Glutamates; 55520-40-6/Tyrosine; 56-12-2/gamma-Aminobutyric Acid; 56-40-6/Glycine; 56-84-8/Aspartic Acid; 56-86-0/Glutamic Acid; 63-91-2/Phenylalanine

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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