| Use of 5,5-(dimethyl)-i-Pr-PHOX as a practical equivalent to t-Bu-PHOX in asymmetric catalysis. | |
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MedLine Citation:
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PMID: 19388656 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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The use of 5,5-(dimethyl)-i-Pr-PHOX as a practical equivalent of t-Bu-PHOX in asymmetric catalysis is reported. This new member of the phosphinooxazoline (PHOX) ligand family behaves similarly in terms of stereoinduction to t-Bu-PHOX with the key advantage of being readily accessible as both enantiomers starting from either (S)- or (R)-valine. |
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Authors:
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Etienne Bélanger; Marie-France Pouliot; Jean-François Paquin |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't |
Journal Detail:
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Title: Organic letters Volume: 11 ISSN: 1523-7052 ISO Abbreviation: Org. Lett. Publication Date: 2009 May |
Date Detail:
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Created Date: 2009-05-07 Completed Date: 2009-06-11 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: United States |
Other Details:
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Languages: eng Pagination: 2201-4 Citation Subset: IM |
Affiliation:
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Organic and Medicinal Chemistry, Département de chimie, Université Laval, Québec, QC, Canada G1V 0A6. |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Catalysis Molecular Structure Oxazoles / chemical synthesis*, chemistry* Stereoisomerism |
| Chemical | |
Reg. No./Substance:
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0/5,5-(dimethyl)-i-Pr-PHOX; 0/Oxazoles |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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