| Unraveling the local energetics of transport in a polymer ion conductor. | |
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MedLine Citation:
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PMID: 23282487 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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We compare diffusion activation energy measurements in a hydrated perfluorosulfonate ionomer and aqueous solutions of triflic acid. These measurements provide insight into water transport dynamics on sub-nm length scales, and gauge the contribution of the polymer sidechain terminal group. Future membrane materials design will hinge on detailed understanding of transport dynamics. |
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Authors:
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Mark D Lingwood; Zhiyang Zhang; Bryce E Kidd; Kacey B McCreary; Jianbo Hou; Louis A Madsen |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-1-3 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2013 Jan |
Date Detail:
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Created Date: 2013-1-3 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Chemistry and Macromolecules and Interfaces Institute, Virginia Tech, Blacksburg, VA, USA. lmadsen@vt.edu. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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