| Unexpected isomerism in "[Pd(2,9-dimethylphenanthroline)X(2)]" (X = Cl, Br, I) complexes: a neutral and an ionic form exist. | |
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MedLine Citation:
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PMID: 22327099 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Complexes of composition "[Pd(2,9-dimethylphenanthroline)X(2)]" (X = Cl, Br, I) have long been known and they are used as precursors for the synthesis of other derivatives or as catalysts. In the previous literature, they have invariably been described as neutral square planar complexes, but we have found that a second ionic isomer also exists, having composition [Pd(Neoc)(2)X](2)[Pd(2)X(6)], and that the formation of this isomer occurs under a wider range of conditions than that of the neutral one. Retrospectively, the ionic isomer had surely been obtained in most previous reports even if formation of the neutral one was claimed. |
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Authors:
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Martino Rimoldi; Fabio Ragaini; Emma Gallo; Francesco Ferretti; Piero Macchi; Nicola Casati |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-2-13 |
Journal Detail:
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Title: Dalton transactions (Cambridge, England : 2003) Volume: - ISSN: 1477-9234 ISO Abbreviation: - Publication Date: 2012 Feb |
Date Detail:
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Created Date: 2012-2-13 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101176026 Medline TA: Dalton Trans Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Università degli Studi di Milano, Dipartimento di Chimica Inorganica, Metallorganica e Analitica "Lamberto Malatesta" and ISTM-CNR, Via Venezian 21, 20133 Milano, Italy. fabio.ragaini@unimi.it. |
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