Document Detail


Unbridged Au(ii)-Au(ii) bonds are theoretically allowed.
MedLine Citation:
PMID:  23321690     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The bonding in the unbridged closed-shell Au(ii)-Au(ii) dimers X(4)Au(2)(C(5)H(5)N)(2), X = H, F-I and CF(3), is analyzed and the short Au-Au bonds around 250 pm are reproduced by a novel 6s6p(z)5d(xy) hybridization.
Authors:
Xiao-Gen Xiong; Pekka Pyykkö
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-16
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-16     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, Tsinghua University, 100 084 Beijing, China.
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