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Two new triterpenoid saponins from Pittosporum senacia Putterlick (Pittosporaceae).
MedLine Citation:
PMID:  23015454     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
From the branches of Pittosporum senacia Putterlick (Pittosporaceae), two new triterpenoid saponins, senaciapittosides A and B (1, 2), were isolated. Their structures were elucidated by extensive analysis of one- and two-dimensional nuclear magnetic resonance spectroscopy, high-resolution electrospray ionization mass spectrometry (HR-ESIMS) and chemical evidence as 3-O-[β- d-glucopyranosyl-(1 → 2)]-[α- l-arabinopyranosyl-(1 → 3)]-[α- l-arabinofuranosyl-(1 → 4)]-β- d-glucuronopyranosyl oleanolic acid 28-O-β- d-glucopyranosyl ester (1) and 3-O-[β- d-glucopyranosyl-(1 → 2)]-[α- l-arabinopyranosyl-(1 → 3)]-[α- l-arabinofuranosyl-(1 → 4)]-β- d-glucuronopyranosyl-22-O-α- l-arabinopyranosyl-21-acetoxy R1-barrigenol (2). Compound 2 presents an unusual glycosylation at C-22 of its aglycone. Copyright © 2012 John Wiley & Sons, Ltd.
Authors:
Jens Linnek; Anne-Claire Mitaine-Offer; Thomas Paululat; Marie-Aleth Lacaille-Dubois
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-9-27
Journal Detail:
Title:  Magnetic resonance in chemistry : MRC     Volume:  -     ISSN:  1097-458X     ISO Abbreviation:  Magn Reson Chem     Publication Date:  2012 Sep 
Date Detail:
Created Date:  2012-9-27     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9882600     Medline TA:  Magn Reson Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 John Wiley & Sons, Ltd.
Affiliation:
EA 4267, FDE/UFC, Laboratoire de Pharmacognosie, Faculté de Pharmacie, Université de Bourgogne, 7 bd. Jeanne d'Arc, BP 87900, 21079, Dijon cedex, France.
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