Document Detail


Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands.
MedLine Citation:
PMID:  23034569     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The first metal coordination complex of a radical ligand based on the 1,2,3-dithiazolyl heterocycle is reported. 6,7-Dimethyl-1,4-dioxo-naphtho[2,3-d][1,2,3]dithiazolyl acts as a bridging ligand in the volatile trinuclear Mn(hfac)(2)-Rad-Mn(hfac)(2)-Rad-Mn(hfac)(2) complex (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato-). The Mn(ii) and radical ligand spins are coupled anti-ferromagnetically (AF) resulting in an S(T) = 13/2 spin ground state.
Authors:
David J Sullivan; Rodolphe Clérac; Michael Jennings; Alan J Lough; Kathryn E Preuss
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-4
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-4     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, University of Guelph, Guelph, ON N1G 2W1, Canada. kpreuss@uoguelph.ca.
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