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Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation.
MedLine Citation:
PMID:  23283246     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Triarylsulfonium hexafluorophosphate salts were shown to be effective catalysts for the ring-opening polymerisation of various cyclic monomers under UV irradiation. A dual basic/acidic catalytic system demonstrated the potential for UV-triggered formation of poly(δ-valerolactone)-b-poly(l-lactide)-b-poly(δ-valerolactone) in a 'one-pot' reaction.
Authors:
Ian A Barker; Andrew P Dove
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-3
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK. a.p.dove@warwick.ac.uk.
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