Document Detail


Transition-metal-mediated activation of the heptaarsenide trianion: isolation of a diaryltetraarsenabutadienediide.
MedLine Citation:
PMID:  23147418     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Reaction of an ethylenediamine solution of K(3)As(7) with the low-valent, low-coordinate cobalt(ii) complex [Co(mes)(2)(PEt(2)Ph)(2)] yielded the novel dianionic species [Co(η(3)-As(3)){η(4)-As(4)(mes)(2)}](2-) (1). The [η(4)-As(4)(mes)(2)](2-) moiety present in 1 is a rare example of a group 15 analogue of a butadienediide.
Authors:
Caroline M Knapp; B H Westcott; M A C Raybould; J E McGrady; J M Goicoechea
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-13
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-13     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford, OX1 3QR, UK. jose.goicoechea@chem.ox.ac.uk.
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