Document Detail


Transfer of Cl ligands between adsorbed Fe-Tetraphenylporphyrin molecules.
MedLine Citation:
PMID:  22746822     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Fe-Tetraphenylporphyrin chloride (FeTPPCl) adsorbed on a Au(111) substrate is investigated using low-temperature scanning tunneling microscopy. Cl is controllably transferred between the Fe center of a selected molecule and the tip of the microscope without disrupting the surrounding molecular pattern. Cl abstraction from FeTPPCl is triggered by removing an electron from the highest occupied molecular orbital. Density functional calculations suggest that the reaction involves a change in the oxidation state of the Fe ion.
Authors:
Thiruvancheril Gopalakrishnan Gopakumar; Hao Tang; Joseph Morillo; Richard Berndt
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-7-2
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  -     ISSN:  1520-5126     ISO Abbreviation:  -     Publication Date:  2012 Jul 
Date Detail:
Created Date:  2012-7-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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