| Tin-free radical carbonylation of alkylsulfonyl derivatives into alkylcarbonyl derivatives. | |
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MedLine Citation:
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PMID: 18666283 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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A simple radical approach based on tin-free radical carbonylation is devised for the direct conversion of alkylthiosulfonates, alkylsulfonyl cyanides, and alkylsulfonyl oxime ethers into the corresponding alkyl thiol esters, acyl cyanides, and acylated oxime ethers in a single step. The present approach is very simple, highly efficient, and minimizes the formation of byproducts. |
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Authors:
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Sangmo Kim; Kyoung-Chan Lim; Sunggak Kim |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Chemistry, an Asian journal Volume: 3 ISSN: 1861-471X ISO Abbreviation: - Publication Date: 2008 Sep |
Date Detail:
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Created Date: 2008-09-25 Completed Date: 2008-11-24 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101294643 Medline TA: Chem Asian J Country: Germany |
Other Details:
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Languages: eng Pagination: 1692-701 Citation Subset: - |
Affiliation:
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Center for Molecular Design & Synthesis and Department of Chemistry, School of Molecular Sciences, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, Korea. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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