Document Detail


Tightly convoluted polymeric phosphotungstate catalyst: an oxidative cyclization of alkenols and alkenoic acids.
MedLine Citation:
PMID:  17371036     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
[reaction: see text] A tightly convoluted polymeric phosphotungstate catalyst was prepared via ionic assembly of H3PW12O40 and poly(alkylpyridinium). An oxidative cyclization of various alkenols and alkenoic acids was efficiently promoted by the polymeric catalyst in aq H2O2 in the absence of organic solvents to afford the corresponding cyclic ethers and lactones in high yield. The catalyst was reused four times without loss of catalytic activity.
Authors:
Yoichi M A Yamada; Haiqing Guo; Yasuhiro Uozumi
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Publication Detail:
Type:  Journal Article     Date:  2007-03-20
Journal Detail:
Title:  Organic letters     Volume:  9     ISSN:  1523-7060     ISO Abbreviation:  Org. Lett.     Publication Date:  2007 Apr 
Date Detail:
Created Date:  2007-04-05     Completed Date:  2007-06-18     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  1501-4     Citation Subset:  -    
Affiliation:
Institute for Molecular Science (IMS), Myodaiji, Okazaki, Aichi 444-8787, Japan.
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