| TiO(2)-assisted photocatalytic degradation of humic acids: effect of copper ions. | |
| | |
MedLine Citation:
|
PMID: 20453331 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
|
The present study investigated the removal efficiency of aqueous humic acid solutions by TiO(2) photocatalytic degradation in the presence of Cu(II) species. The pseudo-first-order kinetics revealed rate constants as 9.87 x 10(-3), 7.19 x 10(-3), 3.81 x 10(-3) min(-1) for Color(436), UV(254) and TOC, respectively. Comparatively, lower rate constants were attained with respect to photocatalytic degradation of humic acid. Considering the source-dependent diverse chemical and spectral characteristics of NOM, a particular interaction would be expected for humic acid with Cu(II) species (0.1 mg L(-1)). The presence of copper ions significantly altered the photocatalytic degradation kinetics of humic acids in relation to the concentration effects of humic acid as expressed by spectroscopic parameters and TOC. Batch equilibrium adsorption experiments revealed a distinct Langmuirian-type adsorptive behavior of humic acid onto TiO(2) both in terms of UV(254) and Color(436) and a C-type adsorption isotherm was attained for TOC. K(F) values displayed an inconsistent effect of Cu(II) species, while adsorption intensity factor 1/n<1 denoted a prevailing favorable type of adsorption for Color(436) and UV(254). Because of the role of intra- and intermolecular interactions between copper ions and humic molecular size fractions, spectroscopic techniques were also employed for the assessment of the adsorption as well as photocatalytic degradation efficiencies. |
| | |
Authors:
|
C S Uyguner; M Bekbolet |
Publication Detail:
|
Type: Journal Article; Research Support, Non-U.S. Gov't |
Journal Detail:
|
Title: Water science and technology : a journal of the International Association on Water Pollution Research Volume: 61 ISSN: 0273-1223 ISO Abbreviation: Water Sci. Technol. Publication Date: 2010 |
Date Detail:
|
Created Date: 2010-05-10 Completed Date: 2010-08-20 Revised Date: - |
Medline Journal Info:
|
Nlm Unique ID: 9879497 Medline TA: Water Sci Technol Country: England |
Other Details:
|
Languages: eng Pagination: 2581-90 Citation Subset: IM |
Affiliation:
|
Bogazici University, Institute of Environmental Sciences, Bebek Istanbul, Turkey. uygunerc@boun.edu.tr |
Export Citation:
|
APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
|
Adsorption Catalysis Copper* Humic Substances* Kinetics Photochemistry / methods* Spectrophotometry Spectrophotometry, Ultraviolet Titanium* |
| Chemical | |
Reg. No./Substance:
|
0/Humic Substances; 13463-67-7/titanium dioxide; 7440-32-6/Titanium; 7440-50-8/Copper |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
Previous Document: Enhanced membrane bioreactor process without chemical cleaning.
Next Document: MTBE degradation by hydrodynamic induced cavitation.