Document Detail


Three Components Chiral Derivatizing Protocols for NMR Spectroscopic Enantiodiscrimination of Hydroxy Acids and Primary Amines.
MedLine Citation:
PMID:  22145800     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The novel three-component chiral derivatization protocols have been derived for 1H and 19F NMR spectroscopic discrimination of a series of chiral hydroxy acids by their coordination and self-assembly with optically active alpha-methylbenzylamine and 2-formylphenylboronic acid. In addition the optically pure (S)-mandelic acid in combination with 2-formylphenylboronic acid permits visualization of enantiomers of primary amines. These protocols have been demonstrated on enantiodiscrimination of chiral amines and hydroxy acids.
Authors:
Sachin Rama Chaudhari; Nagarajarao Suryaprakash
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-12-6
Journal Detail:
Title:  The Journal of organic chemistry     Volume:  -     ISSN:  1520-6904     ISO Abbreviation:  -     Publication Date:  2011 Dec 
Date Detail:
Created Date:  2011-12-7     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2985193R     Medline TA:  J Org Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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