| Three Components Chiral Derivatizing Protocols for NMR Spectroscopic Enantiodiscrimination of Hydroxy Acids and Primary Amines. | |
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MedLine Citation:
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PMID: 22145800 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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The novel three-component chiral derivatization protocols have been derived for 1H and 19F NMR spectroscopic discrimination of a series of chiral hydroxy acids by their coordination and self-assembly with optically active alpha-methylbenzylamine and 2-formylphenylboronic acid. In addition the optically pure (S)-mandelic acid in combination with 2-formylphenylboronic acid permits visualization of enantiomers of primary amines. These protocols have been demonstrated on enantiodiscrimination of chiral amines and hydroxy acids. |
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Authors:
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Sachin Rama Chaudhari; Nagarajarao Suryaprakash |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-12-6 |
Journal Detail:
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Title: The Journal of organic chemistry Volume: - ISSN: 1520-6904 ISO Abbreviation: - Publication Date: 2011 Dec |
Date Detail:
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Created Date: 2011-12-7 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 2985193R Medline TA: J Org Chem Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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