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Thermal decay of TEMPO in acidic media via an N-oxoammonium salt intermediate.
MedLine Citation:
PMID:  21709900     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Disproportionation of TEMPO in acids leads to the formation of an N-oxoammonium salt, which can further decompose under thermal conditions, yielding the corresponding hydroxylamine, N(2)O, CO(2) and a series of dimerisation products. Overall, acid-catalysed thermal decay of TEMPO leads to ca. 80% yield of hydroxylamine.
Authors:
Yun Ma; Colin Loyns; Peter Price; Victor Chechik
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-6-27
Journal Detail:
Title:  Organic & biomolecular chemistry     Volume:  -     ISSN:  1477-0539     ISO Abbreviation:  -     Publication Date:  2011 Jun 
Date Detail:
Created Date:  2011-6-28     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101154995     Medline TA:  Org Biomol Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, University of York, Heslington, York, UKYO10 5DD. victor.chechik@york.ac.uk.
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