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Theoretical description of the electronic structure of the alkali hydride cation NaH+.
MedLine Citation:
PMID:  16839067     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
A theoretical determination of the electronic structure of NaH+ is presented. Potential energy curves and dipole moments have been computed for 48(2)Lambda(+) electronic states (i.e., correlated adiabatically up to Na(6s) + H+) through a model-potential-type method over a wide range of R. Equilibrium distances, transition energies, depths of wells, and/or heights of humps predicted at short and large interatomic separations are reported and compared with available experimental and theoretical values. Variations of the static dipole polarizabilities versus internuclear distance have been determined for the two lowest states.
Authors:
Sylvie Magnier
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  The journal of physical chemistry. A     Volume:  109     ISSN:  1089-5639     ISO Abbreviation:  J Phys Chem A     Publication Date:  2005 Jun 
Date Detail:
Created Date:  2006-07-14     Completed Date:  2007-05-25     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9890903     Medline TA:  J Phys Chem A     Country:  United States    
Other Details:
Languages:  eng     Pagination:  5411-4     Citation Subset:  -    
Affiliation:
I.U.F.M. de Bretagne, 153 rue Saint Malo, CS 54310, F-35042 Rennes Cedex. sylvie.magnier@bretagne.iufm.fr
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