| A Tetracarbene-Oxoiron(IV) Complex. | |
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MedLine Citation:
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PMID: 23193042 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Bioinspired organometallic chemistry: An oxoiron(IV) unit has been trapped within a macrocyclic tetracarbene ligand, merging a key bioinorganic intermediate with a popular organometallic scaffold. The stability of the new complex has allowed its characterization by a variety of methods, which show a strong σ-donating tetracarbene coordination leading to an S=1 ground state and unusual properties of the oxoiron(IV) species. |
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Authors:
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Steffen Meyer; Iris Klawitter; Serhiy Demeshko; Eckhard Bill; Franc Meyer |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-11-28 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2012 Nov |
Date Detail:
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Created Date: 2012-11-29 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Institut für Anorganische Chemie, Georg-August Universität Göttingen, Tammannstr. 4, 37077 Göttingen (Germany) http://www.meyer.chemie.uni-goettingen.de. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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